- Ansa-Metallocenes: Catalysts for the Dehydrocoupling of Hydrosilanes
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The dehydrocoupling of PhMeSiH2 to form oligomers and of PhSiH3 to form polysilanes has been performed with the precatalyst combination of 5-C5H5)2MCl2/nBuLi.
- Shaltout, Raef M.,Corey, Joyce Y.
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p. 4309 - 4320
(2007/10/02)
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- 29Si-Kernresonanzspektren und Synthese von Bromdisilanen und Ioddisilanen
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The syntheses of Bromodisilanes BrnSi2H6-n and Iododisilanes InSi2H6-n (n=1, 2, 3, 4, 5), starting from aryldisilanes ArnSi2H6-n (Ar=phenyl, α-naphthyl, mesityl) are reported.The 29Si-NMR-spectra of all compounds, including 29Si29Si-coupling constants, have been measured.
- Hassler, K.,Bauer, G.
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p. 149 - 154
(2007/10/02)
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