Microwave-assisted cleavage of phosphate, phosphonate and phosphoramide esters
A mild and rapid protocol for cleavage of phosphate, phosphonate and phosphoramide esters. The scope and limitations of this microwave-assisted reaction is explored here.
Protection of phosphate with the 9-fluorenylmethyl group. Synthesis of unsaturated-acyl phosphatidylinositol 4,5-bisphosphate
Alkyl di-(9-fluorenylmethyl) phosphates obtained via phosphitylation were found to be suitable for protection of phosphoric monoesters, which were generated by treatment of the triesters with DBU or triethylamine This strategy and a hydroxyl protecting gr
A process for preparing phosphonic acids of the structure STR1 wherein R1 is lower alkyl, aryl, cycloalkyl or arylalkyl, and R2 is H, benzyl or STR2 by oxidizing the corresponding phosphonous acid STR3 employing as the oxidizing agent potassium permanganate or sodium periodate.
-
(2008/06/13)
More Articles about upstream products of 50577-84-9