- Photolysis of tris(trimethylsilyl)silane: Trapping of sisyl radicals
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The photolysis of tris(trimethylsilyl)silane (TTMSS) was studied in the absence and in the presence of added trapping agents such as alkenes and alcohols. It was found that, unlike the case with pyrolysis, silyl radicals rather than silylenes are produced
- Mohamed, Mustafa,Brook, Michael A.
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p. 1357 - 1362
(2007/10/03)
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- Preparation of oligosilanes containing perhalogenated silyl groups (-SiX3, -SiX2-, >SiX-, X = Cl, Br) and their hydrogenation by stannanes
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Starting from methylphenylsubstituted oligosilanes the disilanes SiX3-SiXi,Me3-i (i = 0, 1, 2; X = Cl, Br), trisilanes SiX2(SiXiMe3-i) (i = 0, 1) and branched tetrasilanes SiX(SiXMe2)3 were synthesized and their behavior towards the Lewis-base catalyzed hydrogenation by stannanes was investigated. In the case of methylchlorodisilanes SiCl3-SiCliMe3-i Si-Si bond cleavage competes with the hydrogenation reaction.
- Herzog,Roewer
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p. 217 - 223
(2007/10/03)
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