51289-08-8Relevant articles and documents
Ruthenium-catalyzed carbonylation of allene: Direct synthesis of methacrylates and methacrylamides
Zhou, Da-Yang,Yoneda, Eiji,Onitsuka, Kiyotaka,Takahashi, Shigetoshi
, p. 2868 - 2869 (2007/10/03)
Carbonylation reactions of allene in alcohols and amines in the presence of a ruthenium carbonyl catalyst under mild conditions gave methacrylates and methacrylamides, respectively, in good yields with an atom economy of 100%.
VINYLOXYETHYL ESTERS OF MONOCARBOXYLIC ACIDS.
Mikhant'eva,Romanova,Mikhan'tev
, p. 1017 - 1022 (2007/10/02)
The authors examine methods of synthesis and the properties of 2-vinyloxyethyl acylates, a little-studied class of organic compounds on which literature information is very limited and which are of interest as possible monomers for synthesis of macromolecular compounds and as synthetic models of natural physiologically active substances. Methods have been devised for synthesis of 2-vinyloxyethyl acylates - potential monomers for synthesis of macromolecular and physiologically active compounds. The structural characteristics of the synthesized compounds were studied. Cationic polymerization of 2-vinyloxyethyl acylates was carried out, and the dependence of the reaction rate and of the properties of the resultant oligomers on the nature of the acyl radical was determined.