Enzymatic alcoholysis of alkoxymethyl alkanoates: A possible approach for the kinetic resolution of tertiary alcohols
The pivaloyloxymethyl and butanoyloxymethyl derivatives of tert-butanol and linalool (1.4) are readily accepted by hydrolases. Linalool derivative 4b is alcoholysed stereoselectively by Candida rugosa lipase (E=9.7).
Franssen, Maurice C.R.,Goetheer, Earl L.V.,Jongejan, Hugo,De Groot, Aede
p. 8345 - 8348
(2007/10/03)
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