159. Metal binding phenomena: Alcoholate aggregates as direct participants in elimination reactions
In solvents of low polarity it is neither a monomolecular nor a dissociated alcoholate species which effects dehydrohalogenation of vic-dihaloalkanes and OTC-dihalocycloalkanes but rather a dimeric, trimeric or tetrameric alcoholate aggregate. This behavior has important implications for the stereochemical outcome of such elimination reactions.
Von Schlosser, Manfred,Jan, Gerald,Byrne, Edeline,Sicher, Jiri
p. 1630 - 1637
(2007/10/12)
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