52078-48-5Relevant articles and documents
STEREO- AND REGIOSELECTIVITY OF THE CATALYTIC SYSTEM MoCl5/SiO2-SnMe4 IN THE REACTION OF METATHESIS AND COMETATHESIS OF OLEFINS AND THEIR FUNCTIONAL DERIVATIVES
Bykov, V. I.,Butenko, T. A.,Finkel'shtein, E. Sh.
, p. 151 - 155 (2007/10/02)
It was shown that the catalytic system MoCl5/SiO2-SnMe4 has almost 100percent regioselectivity with respect to olefins.The stereoselectivity of the system is not a function of the length of the α-olefin chain, temperature, or addition of functional groups (COOEt, Cl).Addition of pentachlorophenoxy and 8-hydroxyquinolyl ligands significantly reduces the activity of the catalytic system with a slight increase in the stereoselectivity with respect to the cis-isomer.
Metathesis of Functionalized Alkenes. Synthesis of Insect Pheromones
Crisp, Geoffrey T.,Collis, Maree P.
, p. 935 - 942 (2007/10/02)
The ability of substituted phenoxy complexes of tungsten to effect metathesis of both functionalized and non-functionalized terminal alkenes has been investigated.This methodology has been applied to the synthesis of the insect pheromones tetradec-9-en-1-yl acetate, dodec-7-en-1-yl acetate and tricos-9-ene.