Hydrosilylation of 2-Phenylpropene with dichloromethylsilane and transformations of the resulting adduct
2-Phenylpropene was hydrosilylated with dichloromethylsilane in the presence of H2PtCl6 to synthesize dichloromethyl(2-phenylpropyl)silane. The latter was reacted with methanol in the presence of carbamide to obtain dimethoxymethyl(2-phenylpropyl)silane, whose reaction with methylmagnesium iodide gave methoxydimethyl(2-phenylpropyl)silane. Treatment of the latter with 40% HF gave fluorodimethyl(2-phenylpropyl)silane which was reacted with BrMgC≡CH to obtain dimethylethynyl(2-phenylpropyl)silane.
Yarosh
p. 1555 - 1556
(2007/10/03)
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