REDOX-BASED REAGENTS FOR METHIONINE BIOCONJUGATION
Chemoselective conjugation is achieved through redox reactivity by reacting an N- transfer oxidant with a thioether substrate in a redox reaction in an aqueous environment to form a conjugation product. In embodiments, Redox-Activated Chemical Tagging (ReACT) strategies for methionine-based protein functionalization. Oxaziridine (Ox) compounds serve as oxidant-mediated reagents for direct functionalization by converting methionine to the corresponding sulfimide conjugation product.
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Paragraph 0120
(2018/05/27)
Intramolecular ring closure in N-propynyl-barbituric acids and N-propynyl-benzamides
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Schulte,Sommer,Reisch
p. 107 - 112
(2007/10/04)
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