ISOMERISATIONS THERMIQUES ORIGINALES DE COMPOSES β-CHLORES DU SILICIUM INDUITES PAR UN GROUPE β'-ETHYLENIQUE
The thermolysis of linear and cyclic β-chloro-β'-ethylenesilicon compounds gives rise to two competitive reactions.Besides the classical β-elimination reaction, a new rearrangement reaction was observed, which depends on the Si-bonded R groups; it has not been noticed for the corresponding germanium compounds.To explain the results, we propose a mechanism involving a transient pentavalent silicon anion.
Manuel, Georges,Bertrand, Guy,Mazerolles, Pierre,Ancelle, Jacques
p. 311 - 323
(2007/10/02)
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