Mild Generation of Alkylidenecarbenes from (Tosylazo)alkenes and Silylvinyl Triflates. Mode of Decomposition and Nature of the Carbene Intermediates
(Tosylazo)alkenes, R2C=CHN=NTs, decomposed in olefin-solvent mixtures both under neutral conditions at room temperature and with amine bases present to produce alkylidenecyclopropanes in moderate to good yields.Diazoalkenes, R2C=C=N2, were implicated as t
Fox, Dennis P.,Bjork, Jon A.,Stang, Peter J.
p. 3994 - 4002
(2007/10/02)
Photochemical Fragmentation of a Methylenecyclopropane
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Gilbert, J. C.,Luo, T.
p. 5237 - 5239
(2007/10/02)
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