53396-33-1Relevant articles and documents
KOtBu-Promoted Transition-Metal-Free Transamidation of Primary and Tertiary Amides with Amines
Ghosh, Tridev,Jana, Snehasish,Dash, Jyotirmayee
supporting information, p. 6690 - 6694 (2019/09/12)
This work discloses transamidation of primary and tertiary amides with a range of aryl, heteroaryl, and aliphatic amines using potassium tert-butoxide. The reaction proceeds at room temperature under transition-metal-free conditions providing secondary amides in high yields. Moreover, reaction of cyclopropyl amine with tertiary amides proceeds with ring-opening to provide a rapid access to enamides.
Supported nano-gold-catalyzed N-formylation of amines with paraformaldehyde in water under ambient conditions
Ke, Zhengang,Zhang, Yan,Cui, Xinjiang,Shi, Feng
, p. 808 - 816 (2016/02/12)
A simple and efficient Au/Al2O3 catalyst was prepared by the co-precipitation method for the oxidative N-formylation of amines with paraformaldehyde. Under the optimized reaction conditions, excellent amine conversion and N-formamide selectivity can be obtained with up to 97% yield with water as the solvent under ambient conditions. This catalyst tolerated a wide range of primary amines and second amines, and it can be reused for at least five runs without obvious deactivation.
Multicomponent synthesis of Ugi-type ceramide analogues and neoglycolipids from lipidic isocyanides
Perez-Labrada, Karell,Brouard, Ignacio,Mendez, Inmaculada,Rivera, Daniel G.
experimental part, p. 4660 - 4670 (2012/07/27)
Unique types of ceramide and glycolipid architectures were obtained by means of Ugi reactions incorporating lipidic isocyanides as surrogates of sphingolipids. The multicomponent nature of this approach allowed for a highly efficient assembly process, whe
Comprehensive investigation of self-assembled monolayer formation on ferromagnetic thin film surfaces
Hoertz, Paul G.,Niskala, Jeremy R.,Dai, Peng,Black, Hayden T.,You, Wei
supporting information; experimental part, p. 9763 - 9772 (2009/02/04)
We report a simple, universal method for forming high surface coverage SAMs on ferromagnetic thin (≤100 nm) films of Ni, Co, and Fe. Unlike previous reports, our technique is broadly applicable to different types of SAMs and surface types. Our data constitutes the first comprehensive examination of SAM formation on three different ferromagnetic surface types using two different surface-binding chemistries (thiol and isocyanide) under three different preparation conditions: (1) SAM formation on electroreduced films using a newly developed electroreduction approach, (2) SAM formation on freshly evaporated surfaces in the glovebox, and (3) SAM formation on films exposed to atmospheric conditions beforehand. The extent of SAM formation for all three conditions was probed by cyclic voltammetry for surfaces functionalized with either (11-thiolundecyl)ferrocene (Fc-(CH2)11-SH) or (11-isocyanoundecyl)ferrocene (Fc-(CH2)11-NC). SAM formation was also probed for straight-chain molecules, hexadecanethiol and hexadecaneisocyanide, with contact angle measurements, X-ray photoelectron spectroscopy, and reflection-absorption infrared spectroscopy (RAIRS). The results show that high surface coverage SAMs with low surface-oxide content can be achieved for thin, evaporated Ni and Co films using our electroreduction process with thiols. The extent of SAM formation on electroreduced films is comparable to what has been observed for SAMs/Au and to what we observe for SAMs/Ni, Co, and Fe samples prepared in the glovebox.
Rapid and Selective Formylation With Pentafluorophenyl Formate
Kisfaludy, Lajos,Oetvoes, Laszlo
, p. 510 (2007/10/02)
Pentafluorophenyl formate reacts smoothly with N-nucleophiles under mild conditions to give the N-formyl derivatives, whereas O- and S-nucleophiles remain unaffected even in the presence of a tertiary base.
