- CHLOROSULFONATION OF SOME COMPOUNDS CONTAINING TWO PHENYL RINGS
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Diphenylmethane (1) and dibenzyl (17) reacted with chlorosulphonic acid to give the corresponding p,p'-disulphonyl chlorides (2,18).However, attempted chlorosulfonations of α-chloro-, αα'-dichlorodiphenylmethane, stilbene and 1,4-diphenylbutadiene were unsuccessful.Diphenylacetic acid reacted with chlorosulfonic acid to give a mixture of 4,4'-dichlorosulfonylbenzophenone (40) and α-chlorodiphenylmethane-4,4'-disulfonyl chloride (39).Benzilic acid (41) afforded 9-chlorofluorene-2,7-disulfonyl chloride (42), which with amines gave 3 different products according to the reaction conditions.Fluorene (53) and the 9-carboxylic acid (43) have been treated with chlorosulfonic acid.The various sulfonyl chlorides were converted into 43 derivatives for biocidal evaluation.Mechanistic interpretations for the reactions is included.
- Cremlyn, Richard,Swinbourne, Frederick J.,Graham, Stephen,Lynch, John M.
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p. 121 - 134
(2007/10/02)
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- Oxyformamidates
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Compounds of the formula STR1 WHEREIN A is a linking group, X is an O--CO-- or --SO2 -- group and n is at least 2, are prepared from the corresponding N',N'-disubstituted hydrazides by quaternization and treatment with alkali or reaction with an alkylene epoxide or from the corresponding compound wherein n = 1 and A is a polymerizable group by polymerization. The compounds are unstable to heat and may be used as cross-linking agents for polymers or as chain-extending agents, bonding agents or adhesives.
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