Photoinduced Cross-Coupling of Aryl Iodides with Alkenes
A protocol for photoinduced cross-coupling of aryl iodides having polar π-functional groups or elongated π-conjugation with alkenes has been developed. The radical cascade mechanism involving generation of aryl radicals via C-I bond homolysis of photoexcited aryl iodides and their subsequent addition to alkenes is proposed. The method enables iodide-selective cross-coupling over other halogen leaving groups with functional group compatibility on both arene and alkene motifs.
Liu, Yuliang,Li, Haoyu,Chiba, Shunsuke
supporting information
p. 427 - 432
(2021/01/26)
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