THE GENERATION OF C,O,O-TRILITHIATED DERIVATIVES OF DIHYDRIC PHENOLS
Halogenated dihydric phenols (hydroquinones and resorcinols) undergo halogen metal exchange with nBuLi/TMEDA/THF or ether (inverse addition) under sonication, thereby generating a C,O,O-trilithiated species which can be trapped with electrophiles.
Saa, Jose M.,Morey, Jeroni,Suner, Guillem,Frontera, Antoni,Costa, Antoni
p. 7313 - 7316
(2007/10/02)
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