- Pentakis(trifluoromethyl)benzenediazonium cation: A useful building block for the syntheis of trifluoromethyl-substituted derivatives
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The sterically crowded, highly electron-deficient diazonium salt C 6(CF3)5N2+ BF 4- has been synthesized and sample dediazotization reactions were carried out. New compounds, C6(CF3) 5I, C6(CF3)5NO2, and C6(CF3)5NO were isolated and identified. Also, a more convenient route to C6(CF3)5NH 2 that gave good yield was achieved. Copyright
- Kuett, Agnes,Werner, Franz,Kaljurand, Ivari,Leito, Ivo,Koppel, Ilmar A.
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p. 932 - 936
(2013/09/24)
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- Pentakis(trifluoromethyl)phenyl, a sterically crowded and electron-withdrawing group: Synthesis and acidity of pentakis(trifluoromethyl) benzene, -toluene, -phenol, and -aniline
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(Figure Presented) A general route to functionalized pentakis(trifluoromethyl)phenyl (C6(CF3)5) derivatives, promising building blocks for designing novel stable carbenes, radical species, superacids, weakly coordinating a
- Kuett, Agnes,Movchun, Valeria,Rodima, Toomas,Dansauer, Timo,Rusanov, Eduard B.,Leito, Ivo,Kaljurand, Ivari,Koppel, Juta,Pihl, Viljar,Koppel, Ivar,Ovsjannikov, Gea,Toom, Lauri,Mishima, Masaaki,Medebielle, Maurice,Lork, Enno,Roeschenthaler, Gerd-Volker,Koppel, Ilmar A.,Kolomeitsev, Alexander A.
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p. 2607 - 2620
(2008/09/19)
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