Phosphino Sulphonates, a Type of PIII-anhydride and Their Isomerisation into Phosphinoyl Sulphinates: a Novel Rearrangement in Phosphorus-Sulphur Chemistry
The imidazolides (1) react smoothly with RSO3H to afford a novel class of trico-ordinate phosphorus anhydride, the phosphino sulphonates (2); under suitable structural circumstances the compounds (2) undergo a novel type of rearrangement, (2) -> (6), which provides the first example of a phosphinoyl sulphinate structure (6).
Dabkowski, Wojciech,Michalski, Jan,Skrzypczynski, Zbigniew
p. 1260 - 1261
(2007/10/02)
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