N,N'-BIS(1-CHLOROALKYL)CARBODIIMIDES. II. REACTIONS WITH PROTON-CONTAINING NUCLEOPHILIC REAGENTS
The reactions of N,N'-bis(1-chloroalkyl)carbodiimides with proton-containing nucleophilic reagents were investigated.It was shown that substitution products retaining the carbodiimide structure are formed in the reactions with alcohols and phenols.The action of water or primary amines is accompanied by fragmentation of the molecule and leads to the production of chloroformamidine or N-substituted guanidines.Secondary amines act on N,N'-bis(1-chloroalkyl)carbodiimides to form diazadienes, which exist as mixtures of Z,E isomers.
Fetyukhin, V. N.,Vovk, M. V.,Pirozhenko, V. V.,Samarai, L. I.
p. 1822 - 1828
(2007/10/02)
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