cas 5466-06-8, Ethyl 3-mercaptopropionate | Articles data

Articles about 5466-06-8Total 8 be found

Method and device for continuously producing thiopropionate series compounds through pipeline type
The invention discloses a method and a device for continuously producing thiopropionate series compounds through pipeline type, and can simultaneously or separately prepare thiodipropionate compounds. Dithionate type compounds and mercapto ester compounds. The method is simple to operate, low in cost and high in yield, and is suitable for industrial production.
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Paragraph 0100; 0103-0105

(2021/11/27)

Synthesis of 2-sulfanylidene-1,3-thiazolidin-4-one derivatives
Three-component condensation of primary amines with carbon disulfide and dialkyl maleates afforded the corresponding alkyl (3-R-4-oxo-2-sulfanylidene-1,3-thiazolidin-5-yl)acetates whose structure was confirmed by independent synthesis and IR and 1/s
Mustafaev,Efendieva, Kh. K.,Akchurina, T. Kh.
p. 1860 - 1863
(2018/02/06)

Eco-friendly combination of the immobilized PGA enzyme and the s-phacm protecting group for the synthesis of cys-containing peptides
Enzyme-labile protecting groups have emerged as a green alternative to conventional protecting groups. These groups introduce a further orthogonal dimension and eco-friendliness into protection schemes for the synthesis of complex polyfunctional organic molecules. S-Phacm, a Cys-protecting group, can be easily removed by the action of a covalently immobilized PGA enzyme under very mild conditions. Herein, the versatility and reliability of an eco-friendly combination of the immobilized PGA enzyme and the S-Phacm protecting group has been evaluated for the synthesis of diverse Cys-containing peptides.
Góngora-Benítez, Miriam,Basso, Alessandra,Bruckdorfer, Thomas,Royo, Miriam,Tulla-Puche, Judit,Albericio, Fernando
supporting information
p. 16166 - 16176
(2013/02/23)

A general and mild synthesis of thioesters and thiols from halides
The conversion of a wide variety of halides to thioesters by reaction with potassium thiocetate under mild conditions is described, and the generality of the method is demonstrated.
Zheng, Tu-Cai,Burkart, Maureen,Richardson, David E.
p. 603 - 606
(2007/10/03)

SYNTHESIS AND HYDROLYTIC STABILITY OF SOME NEW PHOSPHONODITHIOITE, PHOSPHONODITHIOATE, AND PHOSPHONOTRITHIOATE ESTERS
The compounds RP(SCH2CH2CO2CH2CH3)2 (R = (CH3)3C, C6H5) have been prepared from RPCl2 and HSCH2CH2CO2CH2CH3 and base.The compounds react with hydrogen peroxide and with sulfur to give RP(O)(SCH2CH2CO2CH2CH3)2 and RP(S)(SCH2CH2CO2CH2CH3)2 respectively.The 5-membered ring compound has been synthesized from C6H5PCl2 and diethyl 2,3-dimercaptosuccinate and base.The compounds reacts with hydrogen peroxide and with sulfur to give and respectively.Reacting C6H5PCl2 with one equivalent of HSCH2CH2CO2CH2CH3 and base gives C6H5PCl(SCH2CH2CO2CH2CH3), which undergoes hydrolysis to give C6H5PH(O)(SCH2CH2CO2CH2CH3).Except for and C6H5PH(O)(SCH2CH2CO2CH2CH3), the compounds do not undergo significant hydrolytic cleavage of the P-S bond.The hydrolysis of likely proceeds via C6H5PH(O)(SCH(CO2CH2CH3)CH(CO2CH2CH3)SH).The increased hydrolysis rate of C6H5PH(O)(SCH2CH2CO2CH2CH3) is possibly due to hydrogen bonding between water and the PH(O) functionality. Key words: Phosphonodithioite; phosphonodithioate; phosphonotrithioate; hydrogen bonding; NMR spectra.
Kim, Sangha,Mimikakis, John L.,Roundhill, D. Max
p. 119 - 128
(2007/10/02)