CYCLOPROPANE FORMATION FROM 4,5-UNSATURATED THIOPHENYLETHERS. CONVERSION OF LIMONENE INTO CAR-2-ENE
Strong bases can abstract a proton α to a double bond.A phenylthio group γ to that double bond can be eliminated at the same time leading to a cyclopropane ring.The procedure is illustrated by a conversion of limonene into car-2-ene.
Fourneron, J. D.,Harwood, L. M.,Julia, M.
p. 693 - 696
(2007/10/02)
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