- Diarylheptanoid glucosides from Pyrostria major and their antiprotozoal activities
-
Eight new diarylheptanoid glucosides 1-8 have been isolated from the leaves of Pyrostria major (A. Rich & DC.) Cavaco [syn. Canthium major (A. Rich & DC.)] Cavaco. Their structures were determined by 1D and 2D NMR spectroscopic and HRMS analyses. The abso
- Beniddir, Mehdi A.,Grellier, Philippe,Rasoanaivo, Philippe,Loiseau, Philippe M.,Bories, Christian,Dumontet, Vincent,Gueritte, Francoise,Litaudon, Marc
-
experimental part
p. 1039 - 1046
(2012/04/10)
-
- Diarylheptanoids from the Rhizomes of Curcuma xanthorrhiza and Alpinia officinarum
-
Five diarylheptanoids including two new compounds were isolated from the rhizomes of Curcuma xanthorrhiza (Zingiberaceae).The structures of the new compounds were determined to be octahydrocurcumin ((3S, 5S)-1,7-bis(4-hydroxy-3-methoxyphenyl)-heptane-3,5-diol) (Ia) and (1ξ)-1-hydroxy-1,7-bis(4-hydroxy-3-methoxyphenyl)-6-heptene-3,5-dione (II) on the basis of spectral and chemical evidence.The absolute configurations of Ia and a new similar diarylheptanoid, (3R, 5R)-1-(4-hydroxyphenyl)-7-phenylheptane-3,5-diol (VIa), isolated from the rhizomes of Alpinia officinarum (Zingiberaceae), were established by application of the exciton chirality rule.Keywords--diarylheptanoid; Curcuma xanthorrhiza; Alpinia officinarum; Zingiberaceae; (3S, 5S)-1,7-bis(4-hydroxy-3-methoxyphenyl)-heptane-3,5-diol; (1ξ)-1-hydroxy-1,7-bis(4-hydroxy-3-methoxyphenyl)-6-heptene-3,5-dione; (3R, 5R)-1-(4-hydroxyphenyl)-7-phenylheptane-3,5-diol; exciton chirality rule; CD
- Uehara, Shin-ichi,Yasuda, Ichiro,Akiyama, Kazuyuki,Morita, Hiroshi,Takeya, Koichi,Itokawa, Hideji
-
p. 3298 - 3304
(2007/10/02)
-