Chloride-tolerant gold(I)-catalyzed regioselective hydrochlorination of alkynes
We have developed a highly regioselective homogeneous gold(I)-catalyzed anti-hydrochlorination of unactivated alkynes at room temperature. We have overcome the incompatibility between conventional cationic gold catalysts and chloride by using a hydrogen-b
Ebule, Rene,Liang, Shengzong,Hammond, Gerald B.,Xu, Bo
p. 6798 - 6801
(2017/11/09)
Unsymmetrical Alkenes by Carbene Coupling from Diazirine Decomposition in the Presence of Diazo Compounds
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Doyle, Michael P.,Devia, Alvaro H.,Bassett, Kathlene E.,Terpstra, Jan W.,Mahapatro, Surendra N.
p. 1619 - 1621
(2007/10/02)
Stereochemistry of the Reactions of CuI Catalyzed Grignard Reagents with Ethyl (E)- and (Z)-β-Chlorocinnamates
Ethyl (E)- and (Z)-3-chloro-3-phenyl-2-propenoate were prepared and separated.The (Z)-isomer gave β-alkylated ethyl cinnamates in good yield when reacted with alkyl Grignard reagents in the presence of 10percent CuI.The (Z)-isomer reacted with retention o
Jalander, Lars,Broms, Merete
p. 173 - 178
(2007/10/02)
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