- Synergistic Combinations Of Active Ingredients
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The present invention relates to novel active compound combinations comprising, firstly, at least one known compound of the formula (I) in which R1 and A have the meanings given in the description and, secondly, at least one further known active compound from groups (2) to (27) listed in the description, which combinations are highly suitable for controlling animal pests such as insects and unwanted acarids and also phytopathogenic fungi.
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- Synergistic Active Compound Combinations Comprising Phenyltriazoles
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The present invention relates to novel active compound combinations comprising, firstly, at least one known compound of the formula (I) in which R1 and R2 have the meanings given in the description. and at least one further known active compound from groups (2) to (27) listed in the description, which combinations are highly suitable for controlling animal pests such as insects and unwanted acarids and also phytopathogenic fungi.
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- Synergistic Fungidical Active Substance Combinations
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The present invention relates to novel active substance combinations which contain spiroxamine, which is known, a known azole and a known carboxamide and which are very suitable for controlling undesired phytopathogenic fungi.
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- SUBSTITUTED SPIROCYCLIC KETOENOLS
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The present invention relates to novel substituted spirocyclic ketoenols of the formula (I) in which W, X, Y, Z, A, B, D and G are as defined in the disclosure, to a plurality of processes for their preparation and to their use as pesticides, microbicides and herbicides.
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- Glyoxyl acid amides, method for producing them and their use for controlling harmful organisms
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The invention relates to novel gloyoxylic acid amides, to a process for their preparation and to their use for controlling harmful organisms.
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- Use of oxabicyclo[2.2.1]heptane derivatives as pesticidal agents
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7-oxabicyclo[2.2.1]heptane derivatives of formula (I) in which X, R1, R2, R3 and R4 have the meanings set forth in the specification, are very suitable for controlling undesired microorganisms and animal pests. New 7-oxabicyclo[2.2.1]heptane derivatives of formula (Ia) in which X, R1, R2, R3 and R14 have the meanings set forth in the specification, and a process for the preparation of the new compounds.
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- Triazolopyrimidines
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The invention relates to novel triazolopyrimidines of the formula 1wherein X represents halogen, Y represents a hydrogen atom or halogen, and R has the meanings given in the disclosure, to a process for the preparation of the new compounds, and to their use as microbicides.
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- Heterocyclic fluoroalkenyl thioethers and the use thereof as pesticides(III)
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The present invention relates to novel heterocyclic fluoroalkenyl thioethers of the formula (I) in which X represents hydrogen, halogen or alkyl, m represents integers from 3 to 10, n represents 0, 1 or 2, Y represents sulphur or oxygen, R1 represents halogen, represents in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkenyl, alkenyloxy, alkenylthio or alkylcarbonyl, represents optionally substituted cycloalkyl, represents optionally substituted aryl or represents optionally substituted heterocyclyl and R2 represents hydrogen, halogen, represents in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkenyl, alkenyloxy, alkenylthio or alkylcarbonyl, represents optionally substituted cycloalkyl, represents optionally substituted aryl or represents optionally substituted heterocyclyl, ?except for compounds where R1=alkyl, Y=oxygen and X=hydrogen, and to processes for their preparation and to their use as pesticides.
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- Heterocyclic fluoroalkenyl thioethers and the use thereof as pesticides (I)
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The present invention relates to novel heterocyclic fluoroalkenyl thioethers of the formula (I) in which X represents hydrogen, halogen or alkyl, m represents integers from 2 to 10, n represents 0, 1 or 2, Y represents unsubstituted or substituted methylene and p represents 1, 2 or 3. and to processes for their preparation and to their use as pesticides.
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- Substituted imide derivatives
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The present invention relates to novel substituted imide derivatives of the general formula (I) in which R1 represents optionally substituted cycloalkyl, R2 represents optionally substituted alkyl or optionally substituted cycloalkyl, R3 represents alkyl, alkoxy, alkylthio, amino, alkylamino or dialkylamino and R4 represents cyano or nitro, and to processes for their preparation and to their use for controlling animal pests and as herbicides.
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- Substituted 3-thiocarbamoylpyrazoles
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The invention relates to novel substituted 3-thiocarbamoylpyrazoles of general formula (I), wherein m, n, R1, R2, R3and Ar have the meanings cited in the description. The invention further relates to methods for the production and use thereof as pesticides.
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- Isothiazolecarboxylic acid derivatives and their use as microbicides
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Novel isothiazolecarboxylic acid derivatives of the formula (I), in which A, Q, Z and k have the meanings mentioned in the specification, processes for the preparation of the new compounds and their use as microbicides.
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- Heterocylic fluoroalkenyl thioethers and the use thereof as pesticides (IV)
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The present invention relates to novel heterocyclic fluoroalkenyl thioethers of the formula (I) in which m represents integers from 3 to 10, n represents 0, 1 or 2 and Het represents the following, in each case optionally substituted, groupings: and to processes for their preparation and to their use as pesticides.
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- Heterocyclic fluoroalkenyl thioethers (II)
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The present invention relates to novel heterocyclic fluoroalkenyl thioethers of the formula (I) in which X represents hydrogen, halogen or alkyl, m represents integers from 3 to 10, n represents 0, 1 or 2, Het represents the groupings, where R1 represents hydrogen, mercapto, represents in each case optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl or alkenyl, represents optionally substituted aryl or represents optionally substituted heterocyclyl, Y represents oxygen or sulphur, and R2 represents hydrogen, alkyl or optionally substituted aryl, and to processes for their preparation and to their use as pesticides.
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- Arylphenyl-substituted cyclic keto-enols
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The present invention relates to novel arylphenyl-substituted cyclic ketoenols of the formula (I) in whichX represents halogen, alkyl, alkoxy, alkenyloxy, alkylthio, alkylsulphinyl, alkylsulphonyl, halogenoalkyl, halogeno-alkoxy, halogenoalkenyloxy, nitro, cyano or in each case optionally substituted phenyl, phenoxy, phenylthio, phenyl-alkoxy or phenylalkylthio,Y represents in each case optionally substituted cycloalkyl, aryl or hetaryl,Z represents hydrogen, halogen, alkyl, alkoxy, alkenyloxy, halogenoalkyl, halogenoalkoxy, halogenoalkenyloxy, nitro or cyano,CKE represents one of the groups ?in whichA, B, D, G and Q1 to Q6 are each as defined in the description, to a plurality of processes for their use as pesticides and herbicides.
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- 3-phenyl-pyrones
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Novel 3-phenyl-pyrones of the formula in which A, D, X and Y are each as defined in the description, a process for preparing these substances and their use as pesticides, fungicides and herbicides.
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- Utilization of 3-phenyl-pyrones for pest control
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3-Phenyl-pyrones of the formula in which x represents pyrid-2-yl and Y represents fluorine, or x represents 4-fluoro-phenyl and Y represents chlorine, are highly suitable for use as pesticides, fungicides and herbicides.
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- Fungicidal benzoheterocyclyloxime
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The invention relates to novel benzoheterocyclyloximes, to a process for their preparation and to their use as fungicides.
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- Arylphenyl-substituted cyclic keto enols
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The present invention relates to novel arylphenyl-substituted cyclic ketoenols, their preparation and the use of such ketoenols as pesticides and/or herbicides. The novel arylphenyl-substituted cyclic ketoenols are of the formula (I) in which CKE refers to the cyclic ketoenol and W, X, Y and Z are as defined in the specification.
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- Methoximinomethyloxathiazines
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The invention relates to novel methoximinomethyloxathiazines, to two processes for their preparation and to their use as pesticides.
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- Methoximinophenylacetic acid amides
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The invention relates to novel methoximinophenylacetamides, to a process for their preparation and to their use as fungicides.
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- Azine used as fungicides
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The invention relates to novel azines, to a process for their preparation and to their use as fungicides.
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- Use of 5-amino-pyrazol-derivatives for combating micro-organisms
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A method of controlling a plant disease caused by a fungus comprising applying a 5-amino-pyrazole of the formula wherein, R1, R2, R3, R4, R5 and Y are as defined in the specification.
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- Pyrazole carboxanilide fungicide
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Novel pyrazole-carboxanilides of the formula in which X, Y, m and n are each as defined in the description, a process for preparing these substances and their use for controlling undesirable microorganisms.
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- Substituted heterocyclic compounds and their use as fungicides
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The invention relates to novel substituted heterocyclic compounds, to a plurality of processes for their preparation and to their use as fungicides, and to novel intermediates, to a plurality of processes for their preparation and to their use as fungicides.
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- Substituted aminosalicyclic acid amides with fungicidal effect and intermediate products for production thereof
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The invention relates to novel substituted aminosalicylamides, to a plurality of processes for their preparation and to their use as fungicides, and also to novel intermediates and to a plurality of processes for their preparation.
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- Isothiazole carboxylic acid amides and the application thereof in order to protect plants
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Novel isothiazolecarboxamides of the formula in which R is as defined in the description, a plurality of processes for preparing the novel compounds and their use for protecting plants against attack by undesirable microorganisms and animal pests.
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- Fungicidal methoximinomethyldioxazines
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The invention relates to novel methoximinomethyldioxazines, to a plurality of processes for their preparation and to their use as fungicides, and also to novel intermediates and to a process for their preparation.
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- Fungicidal alkoximinomethyldioxazine derivatives
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The invention relates to alkoximinomethyldioxazine compounds and intermediates thereof, and to process for the preparation of the alkoximinomethyldioxazine compounds and intermediates thereof. The alkoximinomethyldioxazine compounds have the structure:
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- Fluoromethoximino compounds
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The invention relates to novel fluoromethoximino compounds, to a process for their preparation and to their use as pesticides, and also to novel intermediates and to a plurality of processes for their preparation.
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- Annulated azole derivatives useful as microbicidal agents
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Novel fused azole derivatives of the formula in which R1, R2, A and G are as defined in the description, and also their acid addition salts and metal salt complexes, a plurality of processes for preparing these substances and their use as microbicides in crop protection and in the protection of materials.
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- Oxyranyle-triazoline thiones and their use as microbicides
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Novel oxiranyl-triazolinethiones of the formula in which R1, R2and R3are each as defined in the description, a process for preparing the novel substances and their use as microbicides in crop protection and in the protection of materials.
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- Methoximinomethyloxadiazines
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A compound of the formula (I) wherein Z represents a moiety selected from the group consisting of cycloalkyl having 3 to 7 carbon atoms in the cycloalkyl moiety or cycloalkylalkyl having 3 to 7 carbon atoms in the cycloalkyl moiety and 1 to 4 carbon atoms in the alkyl moiety, with said cycloalkyl or cycloalkylalkyl being in each case optionally mono- to pentasubstituted by halogen or alkyl; a heterocyclyl group selected from the group consisting of thienyl, pyridyl, furyl, thienylmethyl, pyridylmethyl or furylmethyl, each of which is optionally substituted by halogen, dialkylamino or alkyl having 1 to 4 carbon atoms; an aryl or arylalkyl having in each case 6 to 10 carbon atoms in the aryl moiety and 1 to 4 carbon atoms in Q represents oxygen or sulphur, X represents halogen and The compositions have microbicidal activity.
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- Sulfonyl benzazolones
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Sulphonylbenzazolones of the formula in whichR1, R2, R3, R4, R5 and Q are each as defined in the description.a process for preparing these compounds and their use as microbicides in crop protection and in the protection of materials.
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- Halogen pyrimidines and its use thereof as parasite abatement means
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PCT No. PCT/EP97/00151 Sec. 371 Date Jul. 16, 1998 Sec. 102(e) Date Jul. 16, 1998 PCT Filed Jan. 15, 1997 PCT Pub. No. WO97/27189 PCT Pub. Date Jul. 31, 1997Compounds of the formula (I) in which A represents optionally substituted alkanediyl, R represents in each case optionally substituted cycloalkyl, aryl or benzo-fused heterocyclyl, E represents -CH= or nitrogen, Q represents oxygen, sulphur, -CH2-O-, a single bond, or a nitrogen atom which is optionally substituted by alkyl, and X represents halogen.
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- 1,3-dimethyl-5-fluoro-pyrazole-4-carboxamide derivatives, their preparation and their use as microbicides
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PCT No. PCT/EP97/03692 Sec. 371 Date Jan. 20, 1999 Sec. 102(e) Date Jan. 20, 1999 PCT Filed Jul. 11, 1997 PCT Pub. No. WO98/03486 PCT Pub. Date Jan. 29, 1998The invention concerns 1,3-dimethyl-5-fluoro-pyrazole-4-carboxamides of formula (I) in which R stands for a group of formula(II) or (III), in which: R1 stands for alkyl, cycloalkyl, bicycloalkyl, optionally substituted aryl or optionally substituted aralkyl; m stands for integers from 0 to 3 or two vicinal R1 groups together stand for an alkylene chain with 3 or 4 carbon atoms; R2 stands for alkyl, cycloalkyl, bicycloalkyl, optionally substituted aryl or optionally substituted aralkyl; and n stands for integers from 0 to 3 or two vicinal R2 groups together stand for an alkylene chain with 3 or 4 carbon atoms. The invention further concerns a process for preparing the novel substances, and their use for combating undesirable micro-organisms for plant- and material-protection purposes.
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- Iminoacetic acid amides and their use as pest control agents
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PCT No. PCT/EP96/04345 Sec. 371 Date Apr. 15, 1998 Sec. 102(e) Date Apr. 15, 1998 PCT Filed Oct. 7, 1996 PCT Pub. No. WO97/14673 PCT Pub. Date Apr. 24, 1997Iminoacetamides of the formula (I) in which A represents a single bond or optionally substituted alkylene, Q represents oxygen or sulphur, R1 represents respectively optionally substituted cycloalkyl, cycloalkenyl, aryl or heterocyclyl, R2 represents respectively optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aryl or heterocyclyl, R3 represents hydrogen or respectively optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl, R4 represents respectively optionally substituted cycloalkyl, cycloalkenyl, aryl or heterocyclcyl a process for their preparation, pesticidal compositions containing them, and their use for controlling pests.
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- Alkoxyacrylic acid thiol esters used as fungicides
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PCT No. PCT/EP96/03436 Sec. 371 Date Feb. 10, 1998 Sec. 102(e) Date Feb. 10, 1998 PCT Filed Aug. 5, 1996 PCT Pub. No. WO97/07096 PCT Pub. Date Feb. 27, 1997The invention relates to novel alkoxyacrylic thiol esters, to a plurality of processes for their preparation and to their use as fungicides, and to novel intermediates and to a plurality of processes for their preparation.
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- Use of sulfonyloxadiazolones as microbicides
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PCT No. PCT/EP98/01988 Sec. 371 Date Oct. 14, 1999 Sec. 102(e) Date Oct. 14, 1999 PCT Filed Apr. 6, 1998 PCT Pub. No. WO98/47369 PCT Pub. Date Oct. 29, 1998Sulphonyloxadiazolones of the formula in which A represents a single bond or represents alkanediyl, alkenediyl, alkinediyl or a grouping -*O-CH2-, -*O-CH2-CH2-, -*CH2-O-, -*CH2-O-CH2-CH2-, -*CH2-S-, -*S-CH2-, or where the atom labelled by * is in each case attached to R1 and R3 represents hydrogen or alkyl, R1 represents hydrogen, optionally substituted cycloalkyl, optionally substituted cycloalkenyl, optionally substituted aryl or optionally substituted heterocyclyl and R2 represents in each case optionally substituted alkyl, alkenyl, dialkylamino, aryl or heterocyclyl, are highly suitable for controlling undesirable microorganisms in crop protection and in the protection of materials. Novel sulphonyloxadiazolones of the formula in which A and R1 are as defined above and R4 represents optionally substituted alkyl, optionally substituted alkenyl, dialkylamino, nitro-substituted phenyl which may also contain one or two further substituents, or represents optionally substituted heterocyclyl, but where R4 does not represent propyl if A represents a direct bond and R1 represents 2,4,5-trimethyl-phenyl, and a process for preparing these substances.
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- Sulphonyloxadiazolones
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Novel sulphonyloxadiazolones of the formula STR1 in which A represents oxygen, sulphur, --SO--, --SO2 -- or STR2 where R3 represents hydrogen or alkyl, R1 represents optionally substituted cycloalkyl, optionally substituted cycloalkenyl or optionally substituted aryl and R2 represents in each case optionally substituted alkyl, alkenyl, dialkylamino or aryl a process for preparing these substances and their use as microbicides in crop protection and in the protection of materials.
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- Dihydrofuran carboxamides
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The invention concerns novel dihydrofuran carboxamides of formula (I), STR1 in which R stands for groups of formulae (a), (b) or (c), STR2 in which R1, R2, R3, X, m, n and p have the meanings given in the description. The invention also concerns a process for preparing the novel substances, and their use for combating undesirable micro-organisms for plant- and material-protection purposes.
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- Sulphonyloxadiazolones and their use as microbicides
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PCT No. PCT/EP98/01989 Sec. 371 Date Oct. 13, 1999 Sec. 102(e) Date Oct. 13, 1999 PCT Filed Apr. 6, 1998 PCT Pub. No. WO98/47897 PCT Pub. Date Oct. 29, 1998Novel sulphonyloxadiazolones of the formula in which A represents oxygen, sulphur, -SO-, -SO2- or where R3 represents hydrogen or alkyl, R1 represents optionally substituted cycloalkyl, optionally substituted cycloalkenyl or optionally substituted aryl and R2 represents optionally substituted heterocyclyl, a process for preparing these substances and their use as microbicides in crop protection and in the protection of materials.
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- Hydrazonoacetic acid amides and the use thereof as pesticides
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The invention concerns hydrazonoacetic acid amides of general formula (I), a process for producing them, and the use of the said amides as pesticides. In the formula shown, the following meanings apply: A stands for a simple bond or optionally substituted alkylene; Q stands for oxygen or sulphur, R1 stands for optionally substituted cycloalkyl, cycloalkenyl, aryl or heterocyclyl; R2 stands for hydrogen or optionally substituted alkyl, cycloalkyl, cycloalkenyl, aryl or heterocyclyl; R3 and R4 are identical or different and each stand for hydrogen or optionally substituted alkyl or cycloalkyl; R2 and R3 together with the nitrogen atom to which they are bound form an optionally substituted heterocyclyl ring; R5 stands for optionally substituted cycloalkyl, cycloalkenyl, aryl or heterocyclyl.
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- Halogen alkenyl azolyl microbicides
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Novel halogenoalkenyl-azolyl derivatives of the formula STR1 in which R1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl, optionally substituted aryl or represents optionally substituted heteroaryl, R2 represents alkyl, halogenoalkyl, 1-hydroxyalkyl, 2-hydroxyalkyl, 1-hydroxyhalogenalkyl, 1-alkenyl or 2-alkenyl, X1 represents fluorine, chlorine, bromine or iodine, X2 represents fluorine, chlorine, bromine or iodine, and Y represents nitrogen or a CH group, and addition products thereof with acids or metal salts are very active as microbicides in plant protection and in the protection of materials.
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- Microbicidal compositions based on dibromo-thiophene-carboxylic acid derivatives
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New microbicidal compositions based on dibromo-thiophene-carboxylic acid derivatives which are known in some cases, of the formula STR1 in which R represents the groups --XR1, --NR2 R3, --NR4 OR5 or --NR4 --N(R5)2, where X represents oxygen or sulphur and R1, R2, R3, R4 and R5 have the meanings indicated in the description, and the use of these substances for controlling undesired microorganisms. New dibromo-thiophene-carboxylic acid derivatives of the formula STR2 in which R9 represents the groups --SR1, --OR10, STR3 in which R1, R4, R5, R10, R11, R12 and R13 have the meaning indicated in the description, and processes for the preparation of the substances of the formula (I-A).
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- Substituted arylazadioxacyclo alkene fungicides
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The invention relates to novel substituted arylazadioxacycloalkenes, a plurality of processes for their preparation and to their use as fungicides.
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- Solid formulations
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New solid formulations of A) at least one agrochemical active compound, B) at least one additive from the groups mentioned in the description, C) at least one dispersant, D) at least one carrier and E) if appropriate, further active compounds and/or additives, a process for preparing the solid formulations and their use for treating plants. A new device for preparing new granules.
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- A Facile Synthesis of Ketene O,N-Acetals and Ketene O,O-Acetals by Tosylate Elimination
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Reaction of the alcohols 4 and 5 with p-toluensulfonyl chloride leads to the sulfonic esters 6 and 7, respectively, which on treatment with potassium tert-butylate easily react to give the ketene O,N-acetals 8 and O,O-acetals 9, respectively.The (E/Z) isomers 8 arising from the elimination reaction of 7 were identified by their 1H-NMR data after X-ray analysis of one of the isomers of 8e.On one example it is shown that the elimination reaction proceeds stereoselectively "anti".
- Reuther, Wolfgang,Ruland, Alfred,Baus, Ulf
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p. 235 - 240
(2007/10/02)
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- Preparation of 1-azolyl-3,3-dimethyl-1-phenoxybutan-2-ols
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A process for the preparation of a 1-azolyl-3,3-dimethyl-1-phenoxybutan-2-ol of the formula STR1 in which X is a nitrogen atom or the CH group, Y is halogen, alkyl, alkoxycarbonyl, nitro or optionally substituted phenyl, and n is 0,1,2 or 3. comprising reacting a 1-azolyl-3,3-dimethyl-1-phenoxybutan-2-one of the formula STR2 with a secondary alcoholate under pressure in the presence of a diluent. Advantageously the reaction is carried out at a temperature about 20° to 40° C. above the boiling point of the diluent which is a secondary alcohol, the alcoholate is aluminum isopropylate and is present in about 0.35 to 0.4 mol per mol of ketone, and the reaction is carried out under an excess pressure of about 1.5 to 5 bar.
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