Palladium-Catalyzed Intermolecular Vinylation of Cyclic Alkenes
Vinylic halides or triflates and cyclic alkenes undergo facile, palladium-catalyzed, intermolecular, allylic cross-coupling under mild reaction conditions to afford excellent yields of 1,4-dienes.
Larock, Richard C.,Gong, William H.
p. 2047 - 2050
(2007/10/02)
THE PALLADIUM-CATALYSED CROSS-COUPLING REACTION OF 1-ALKENYLBORANES WITH ALLYLIC OR BENZYLIC BROMIDES. CONVENIENT SYNTHESIS OF 1,4-ALKADIENES AND ALLYLBENZENES FROM ALKYNES VIA HYDROBORATION
The reaction of allylic or benzylic bromides with 1-alkenyldisiamylboranes readily available from 1-alkynes in the presence of sodium hydroxyde and catalytic amounts of tetrakis-(triphenylphosphine)palladium to give corresponding 1,4-alkadienes or allylbe
Miyaura, Norio,Yano, Takashi,Suzuki, Akira
p. 2865 - 2868
(2007/10/02)
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