5598-38-9Relevant articles and documents
Synthesis of phosphatidylcholine having a very long chain polyunsaturated fatty acid
Haider, Syed Shabbir,Tanaka, Masatoshi,Alam, Md Khorshed,Nakajima, Shuhei,Baba, Naomichi,Shimizu, Sakayu
, p. 175 - 176 (2007/10/03)
A phosphatidylcholine 9 bearing icosadienoyl and docosahexaenoyl groups at the 1-and 2-positions respectively was synthesized. The synthetic route involves carbon chain elongation of linoleic acid via malonic ester synthesis, preparation of lyso-phosphatidylcholine via lipase-catalyzed mono-acylation of 2-O-methoxyethoxymethylglycerol and phosphodiester synthesis, and finally DCC-mediated esterification.
SPECIFICITY OF THE ENZYME SYSTEM PRODUCING LONG CHAIN ALDEHYDES IN THE GREEN ALGA, ULVA PERTUSA
Kajiwara, Tadahiko,Yoshikawa, Hiroshi,Matsui, Kenji,Hatanaka, Akikazu,Kawai, Tetsuo
, p. 407 - 410 (2007/10/02)
The greater part of the enzyme activity producing long chain aldehydes (LCA) such as (8Z)-heptadecanal, (8Z,11Z)-heptadecadienal, (8Z,11Z,14Z)-heptadecatrienal was found in the 4000 g precipitate of homogenates of the green alga, Ulva pertusa.The LCA-forming activity was readily solubilized from the precipitate by addition of 0.2percent Triton X-100.The solubilized LCA-forming activity showed an optimum pH in the range 8.5-9.5. α-Linolenic acid was a very good substrate, but γ-linolenic acid was a poor substrate for the activity.Linoleic acid was the best substrate of an entire series of (ζ6Z, ζ9Z)-dienoic acids, in which the chain length varied from C13 to C20.Key Word Index - Ulva pertusa; green alga; odour; aldehydes; fatty acids; substrate specificity.