56782-22-0Relevant articles and documents
Hexacarbonylmolybdenum(0)-Catalyzed Reductive Coupling of Allylic Acetates
Masuyama, Yoshiro,Otake, Kiyotaka,Kurusu, Yasuhiko
, p. 1527 - 1528 (2007/10/02)
The reaction of allylic acetates with zinc in the presence of a catalytic amount of hexacarbonylmolybdenum(0) led to reductive coupling for the formation of a 1,5-diene framework.Reductive coupling of nerolidyl acetate provided squalene and its isomers in high yield.
Complexes η3-allylpalladium : isomerisation et photolyse ; synthese du squalene
Muzart, J.,Pete, J. P.
, p. 56 - 58 (2007/10/02)
Complexation of primary allylic chlorides in the presence of Pdo may lead to a mixture of syn and anti η3-allylpalladium complexes.Photolysis or thermolysis also causes syn-anti isomerisation.A mixture of squalene stereoisomers is obtained by photolysis of the η3-farnesylpalladium complexes.