Transition metal complexes-catalyzed synthesis of 2,4,7,9- tetraoxadecane and homologs
Polyether molecules are readily available from cheap acetals with a catalyst system based on ruthenium and tin(II) chloride. As a model reaction 1,3-dioxolane 2 reacts with dimethoxymethane 3 to yield 78% of 2,4,7,9- teetraoxadecane 1.
Fontaine,Piette,Noels,Beaujean,Detry
p. 3153 - 3156
(2007/10/03)
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