Synthesis of a soluble fullerene-rotaxane incorporating a furamide template
The synthesis of a fullerene-rotaxane is described. The thread is constituted by a C60 unit, which acts as a stopper, functionalized with a solubilizing side chain by 1,3 dipolar cycloaddition. The rotaxane is assembled by hydrogen bond-assiste
Light-responsive peptide [2]rotaxanes as gatekeepers of mechanised nanocontainers
Novel mechanized silica nanoparticles incorporating a peptide-based molecular shuttle as a photo-responsive interlocked gatekeeper of nanocontainers are described including the uptake and delivery studies of a model cargo.
Martinez-Cuezva,Valero-Moya,Alajarin,Berna
supporting information
p. 14501 - 14504
(2015/09/28)
Remarkable positional discrimination in bistable light- and heat-switchable hydrogen-bonded molecular shuttles
A tale of two stations: Molecular shuttles, in which a macrocyclic unit can move between two stations over a relatively large distance (1.5 nm), exhibit bistability that can be induced using either light or heat as stimuli, and exhibit large required vari
Altieri, Andrea,Bottari, Giovanni,Dehez, Francois,Leigh, David A.,Wong, Jenny K. Y.,Zerbetto, Francesco
p. 2296 - 2300
(2007/10/03)
Chiroptical Switching in a Bistable Molecular Shuttle
Although various methods for switching the positions of macrocycles in bistable rotaxane-based molecular shuttles have been developed, exploiting such movements to trigger property changes has thus far received little attention. Here we describe one of th
Bottari, Giovanni,Leigh, David A.,Perez, Emilio M.
p. 13360 - 13361
(2007/10/03)
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