Primary alkyl bromides from dimethylthiocarbamates
The conversion of primary alkyl dimethylthiocarbamates into alkyl bromides using the Vilsmeier reagent occurs in high yields in the presence of other non-acid sensitive and non-nucleophilic functional groups. Georg Thieme Verlag Stuttgart · New York.
Moynihan, Meghan F.,Tucker, Joseph W.,Abelt, Christopher J.
experimental part
p. 3565 - 3568
(2009/06/18)
Synthesis of Five-Membered Cyclic Ketones Using Potassium Tetracarbonylferrate(2-)
Various five-membered cyclic ketones prepared from 1,4-dihaloalkanes and potassium tetracarbanylferrate(2-) in moderate to high yields.However, the yields of six- or seven-membered cyclic ketones from the corresponding dihalides were rather low.