- Thermal Analysis Study of Phase Transformations of Magnesium and Calcium Methanesulfonates
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Abstract: Anhydrous magnesium methanesulfonate (Mg(SO3CH3)2) and calcium methanesulfonate (Ca(SO3CH3)2) as well as hydrates Mg(SO3CH3)2 · 2H2O an
- Kosova, D. A.,Kuzovchikov, S. V.,Provotorov, D. I.,Uspenskaya, I. A.
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p. 752 - 757
(2020/06/18)
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- Lanthanide replacement in organic synthesis: Luche-type reduction of α,β-unsaturated ketones in the presence of calcium triflate
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Development of a calcium-mediated regioselective 1,2-reduction of challenging α,β-unsaturated ketones, such as 2-cyclopententone, is reported. The corresponding allylic alcohols are obtained in very good regioselectivities using Ca(OTf)2 and NaBH4. Furthermore, we have shown that our method can stereoselectively reduce aziridinyl ketones.
- Forkel, Nina V.,Henderson, David A.,Fuchter, Matthew J.
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supporting information; experimental part
p. 2129 - 2132
(2012/09/08)
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