ARENES FROM ALKANES OR CYCLOALKANES THROUGH DEHYDRATION OR REARRANGEMENT WITH PYRIDINIUM CHLORIDE
The preparations of various kinds of arylacetic acids both from the precursors and from the synthetic equivalents of (2-oxocyclohexenyl)acetic acids are reviewed.Particular attention is paid to the methods by which these intermediates can be obtained since the usefulness of the reaction is obviously bound to substrate availability.Further developments in the field of aromatic hydrocarbons and heterocyclic compounds are illustrated and a model for the reaction is proposed.In addition to the data already published in scientific journals and in the patent literature, several unpublished data are reported.
Baiocchi, Leandro,Giannangeli, Marilena,Bonanomi, Michele,Picconi, Giuseppe,Ridolfi, Pietro
p. 199 - 216
(2007/10/02)
Process for preparing 2-(substituted phenyl)propionic acids
Preparing 2-(substituted phenyl)propionic acids by heating a mixture containing succinic acid anhydride with a 2-(2-oxo-3-cyclohexenyl)propionic acid derivative and then recovering the 2-(2-substituted phenyl)propionic acid derivative from the reaction mixture. The heated mixture can also contain other acids such as an 2-(1-carboxy-2-oxo-3-cyclohexenyl)propionic acid.
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(2008/06/13)
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