Vicinal tricarbonyls as redox-controlled molecular rotors
Using electrochemistry, spectroelectrochemistry and density functional computational methods, we have demonstrated that tricarbonyl amide 1(ox) undergoes reversible conformational switching upon reduction to the corresponding radical anion 1(rad-). (C) 20
Galow,Cuello,Rotello
p. 9489 - 9492
(2007/10/03)
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