- Preliminary chemical reduction for synthesizing a stable porous molecular conductor with neutral metal nodes
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Preliminary chemical reduction of naphthalenediimide (NDI)-based organic ligands was applied to the synthesis of a porous molecular conductor (PMC) with neutral metal nodes (cobalt(ii) acetylacetonate). The obtained semiconductive PMC (PMC-2) was stable due to the neutral metal nodes, providing an advantage over electrochemical reduction. This journal is
- Koyama, Shohei,Tanabe, Tappei,Takaishi, Shinya,Yamashita, Masahiro,Iguchi, Hiroaki
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supporting information
p. 13109 - 13112
(2020/11/09)
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- Alkali metal salt solvation study in 1,1,3,3-tetramethylurea using nuclear magnetic resonance spectroscopy
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The solution behavior of a series of alkali metal tetraphenylborates, perchlorates, and iodides in 1,1,3,3-tetramethylurea (TMU) has been studied by proton nuclear magnetic resonance (NMR) spectroscopy.TMU has a simple proton NMR spectrum consisting of one singlet at 2.75 ppm.Alkali metyl tetraphenylborates and perchloates were observed to be dissociated in TMU.Sodium iodide, however, was observed to be associated in TMU.Present results are compared with those from other NMR investigations in TMU and related nonaqueous solvents.Key words: alkali metal salt solvation, tetramethylurea; nuclear magnetic resonance, solute-solvent interactions
- Ciolino, Laura Ann,Barker, Barbara Jane
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p. 2206 - 2208
(2007/10/02)
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- Solubilities of Salts and Kinetics of Reactions involving Inorganic Complex Ions in Aqueous Acetone Mixtures
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Solubilities of salts, including those formed by complex ions, are reported for aqueous solutions and for solutions in aqueous acetone mixtures.Data from many sources are combined to yield transfer chemical potentials for an extensive range of ions (at 29
- Blandamer, Michael J.,Briggs, Barbara,Burgess, John,Guardado, Pilar,Radulovic, Stojan,Hubbard, Colin D.
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p. 1243 - 1258
(2007/10/02)
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