Convergent synthesis of the polyene macrolide (-)-roxaticin
(-)-Roxaticin has been synthesized from polyol tetraacetonide 5, which was prepared by a threefold convergent route. Each of the optically pure building blocks (2, 3, and 4) was prepared using a Noyori asymmetric hydrogenation. Sequential alkylation of di
Rychnovsky, Scott D.,Hoye, Rebecca C.
p. 1753 - 1765
(2007/10/02)
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