A facile enantioselective synthesis of 2-(2-aminoethyl)allylsilanes, new synthons for piperidine synthesis
The synthesis of chiral (2-substituted-2-aminoethyl)allylsilanes by cerium mediated trimethylsilylmethylmagnesium chloride addition to the ester group of non racemic chiral β-aminoesters is described.
Monfray, Jérémy,Gelas-Mialhe, Yvonne,Gramain, Jean-Claude,Remuson, Roland
p. 5785 - 5787
(2007/10/03)
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