- SYNTHESIS OF UNSATURATED NITRILES FROM TRISUBSTITUTED OLEFINS VIA ENE-TYPE CHLORINATION
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Unsaturated nitriles have been synthesized from trisubstituted olefins via ene-type chlorination and regioselective substitution with cyanide ion followed by double bond migration.
- Suzuki, Shigeaki,Fujita, Yoshiji,Nishida, Takashi
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p. 817 - 826
(2007/10/02)
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- A New Olefin Synthesis. Synchronous Elimination of Nitro and Ester Groups or Nitro and Keto Groups from β-Nitro Esters or β-Nitro Ketones
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A new synthesis of α,β-unsaturated nitriles (13), esters (14), ketones (15), or sulfones (16) 1R2C=CR3Y, Y = CN (13), Y = COOEt (14), Y = C(=O)R (15), Y = SO2R (16)> starting from α-bromonitroalkanes (1) or α-chloronitro
- Ono, Noboru,Tamura, Rui,Eto, Hiromichi,Hamamoto, Isami,Nakatsuka, Tamon,et al.
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p. 3678 - 3684
(2007/10/02)
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