- Baeyer-Villiger-type Oxidation of an Immonium Group: The Structural Establishment of Naturally Occurring Amides Related to Benzophenanthridine Alkaloids
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Structures of four new amide-alkaloids, arnottianamide (1), isoarnottianamide (2), integriamide (3), and iwamide (4), which occur naturally in Xanthoxylum plants, were established by derivation from the known benzophenanthridine alkaloids chelerythrine (5), nitidine (6), avicine (7), and decarine (8).In these transformations, the novel Baeyer-Villiger-type oxidation of an immonium group was applied.
- Ishii, Hisashi,Ishikawa, Tsutomu,Lu, Sheng-Teh,Chen, Ih-Sheng
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p. 1769 - 1774
(2007/10/02)
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