Synthesis of the AB subunit of angelmicin B through a tandem alkoxy radical fragmentation-etherification sequence
(Chemical Equation Presented) The synthesis of the tricyclic enone 2, corresponding to the AB subunit of the novel tyrosine kinase inhibitor angelmicin B, is described. The strategy centers on an intramolecular Diels-Alder (IMDA) reaction on triene 4 to p
Li, Jialiang,Todaro, Louis J.,Mootoo, David R.
supporting information; experimental part
p. 1337 - 1340
(2009/05/11)
Highly stereoselective synthesis of a seven-membered carbasugar via triisobutylaluminium promoted Claisen rearrangement
2-Methylene-5-vinyl-tetrahydrofuran derivative 6 was obtained from α-D-glucose. Treatment of 6 with triisobutylaluminium (TIBAL) induced Claisen expansion reaction to give the seven-membered carbasugar derivative 7, which represents a new type of chiral b
Jia, Cai,Zhang, Yongmin,Zhang, Lihe
p. 2195 - 2199
(2007/10/03)
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