A general and stereoselective method for synthesis of tri- and tetrasubstituted alkenes
A convenient, general and stereoselective synthesis of trisubstituted alkenes and tetrasubstituted alkenes containing a cyanide function as well as trisubstituted episulphides have been elaborated. Methodology described for the preparation of these compounds is based on the corresponding readily available selenophosphates 1 and thiophosphates 2.
Macia?giewicz,Dybowski,Skowrońska
p. 6057 - 6066
(2007/10/03)
A new synthesis of tri- and tetrasubstituted olefins based on thio- and selenophosphates
Stereoselective synthesis of tri- and tetrasubstituted functionalized olefins and new phosphates bearing functionalized cyclic substituent has been developed using thiophosphates and selenophosphates as key intermediates.