Intramolecular concerted insertion of vinyl cations into C-H bonds: Hydroalkylating cyclization of alkynes with alkyl chloroformates to give cyclopentanes
(Chemical Equation Presented) Tying the knot: In analogy to singlet carbenes, vinyl cations insert into C-H bonds in a concerted intramolecular reaction, as shown by experimental investigations and quantum mechanical calculations. This reaction is useful for the synthesis of cyclopentane derivatives.
Biermann, Ursula,Koch, Rainer,Metzger, Juergen O.
p. 3076 - 3079
(2007/10/03)
More Articles about upstream products of 61142-68-5