Generation of Phosphonium Sites on Sulfated Zirconium Oxide: Relationship to Br?nsted Acid Strength of Surface -OH Sites
The reaction of (tBu)2ArP (1a-h), where the para position of the Ar group contains electron-donating or electron-withdrawing groups, with sulfated zirconium oxide partially dehydroxylated at 300 °C (SZO300) forms [(tBu)2ArPH][SZO300] (2a-h). The equilibrium binding constants of 1a-h to SZO300 are related to the pKa of [(tBu)2ArPH]; R3P that form less acidic phosphoniums (high pKa values) bind stronger to SZO300 than R3P that form more acidic phosphoniums (low pKa values). These studies show that Br?nsted acid sites on the surface of SZO300 are not superacidic.
Rodriguez, Jessica,Culver, Damien B.,Conley, Matthew P.
The invention discloses a method for synthesizing four fluoboric acid di-tert-butyl phenyl [...] method, which belongs to the field of organic synthesis. In the oxygen free atmosphere, phenyl chloride to the phosphine is raw materials, by diisobutyl hydro
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Paragraph 0008; 0009; 0010; 0011
(2019/04/02)
Process for preparing tertiary phosphines
The invention relates to a process for synthesizing tertiary phosphines by reacting halophosphines with organomagnesium compounds in the presence of copper compounds and optionally of salts.
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Page 10
(2008/06/13)
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