Studies towards the synthesis of azadirachtin: Enantioselective entry into the azadirachtin framework through cascade reactions
The carbon framework of azadirachtin (1) has been prepared enantioselectively: The synthesis of compounds 2a-c follows two novel cascade sequences based on intramolecular radical reactions and acid-mediated redox chemistry. Such advanced intermediates sho
Nicolaou,Roecker,Monenschein, Holger,Guntupalli, Prasuna,Follmann, Markus
p. 3637 - 3642
(2007/10/03)
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