- REACTIONS OF 2-AMINO-4,5-BENZO-1,3,2-DIOXAPHOSPHOLANE WITH CARBOXYLIC AND PHOSPHOROUS ACIDS AND ACETIC ANHYDRIDE
-
The reactions of 2-amino-4,5-benzo-1,3,2-dioxaphospholane with acetic acid, benzoic acid, and acetic anhydride yield 2-trimethylsiloxy-4,5-benzo-1,3,2-dioxaphospholane.Upon reaction with dialkyl phosphites, the silylamidophosphite acts as a silylating agent.
- Pudovik, M. A.,Kibardina, L. K.,Pudovik, A. N.
-
p. 214 - 216
(2007/10/02)
-
- PHOSPHORYLATION OF DISILYLATED CARBOXAMIDES
-
The reaction of phosphorus(III) acid chlorides and dichlorides with disilylated carboxamides leads to the formation of mono- and bis-(trimethylsilyl)phosphites.The reactions of diethyl phosphorochloridate, O,O-diethyl phosphorochloridothioate, methylphosphonic dichloride, and phosphoryl chloride with disilylated acetamide proceed with the replacement of chlorine atoms by trimethylsiloxy groups.It was shown that β breakdown can occur in the P(S)-N=P-OSiMe3.
- Pudovik, M. A.,Kibardina, L. K.,Pudovik, A. N.
-
p. 960 - 964
(2007/10/02)
-