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61865-50-7

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Biocatalytical Transformations- VI. The 4-Acetamido-cyclopent-2-ene Carboxylate Route Revisited: Synthesis of (+)- and (-)-Aristeromycin
Enantiomerically pure (+)-as well as (-)-aristeromycin can be synthesized starting from (+)- or (-)-butyl (or hexyl) 4-acetamido-cyclopent-2-ene carboxylate; these carboxylates are easily obtained from their corresponding racemates by hydrolysis with the lipase from Candida rugosa.
Csuk, Rene,Doerr, Petra
p. 5789 - 5798
(2007/10/02)

Carbocyclic Sugar Amines: Synthesis and Stereochemistry of Racemic α- and β-Carbocyclic Ribofuranosylamine, Carbocyclic Lyxofuranosylamine, and Related Compounds
The facile and stereoselective synthesis of racemic carbocyclic β-ribofuranosylamine, carbocyclic β-lyxofuranosylamine, and related 2,3-cis-dihydroxy carbocyclic pentofuranosylamines is reported.In addition, the synthesis, isolation, and base-catalyzed epimerization of methyl cis-4-aminocyclopent-2-enecarboxylate are described.The epimerization at C(1) followed by stereoselective cis hydroxylation provides for the first time access to the racemic carbocyclic α-pentofuranosylamines.
Kam, Bernard L.,Oppenheimer, Norman J.
p. 3268 - 3272
(2007/10/02)

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Chemical Properties

Melting Point: 78-80oC(lit.)
Boiling Point: 221 °C(lit.)
Solubility:H2O: 0.5 g/mL, Hazen ≤50
Vapor Pressure: 1 mm Hg ( 65 °C)
PSA: 55.40000
LogP: 1.02120

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