Correlation of Alkyl and Polar Groups in the Gas-Phase Pyrolysis Kinetics of β-Substituted Ethyl Chloride
The gas-phase pyrolysis kinetics of several β-alkyl-substituted ethyl chlorides were studied in a static system over the temperature range of 400.1-470.1 deg C and a pressure range of 32-317 torr.The reactions in seasoned vessels, with the radical chain i
Chuchani, Gabriel,Martin, Ignacio,Rotinov, Alexandra,Hernandez A., Jose A.,Reikonnen, Nadejda
p. 1563 - 1566
(2007/10/02)
Studies on Sulphochlorination of Paraffins. IX. Regularities of the Sulphochlorination of Branched-chain Paraffins
In the cases of 2-methylbutane and 2-methylpentane the formation of tertiary sulphochlorides in the sulphochlorination of the parent hydrocarbons could be established by means of 13C-n.m.r.-spectroscopy.The relative rates of the various C-H-bonds in 2-methylbutane, 2-methylpentane and 3-methylpentane in the sulphochlorination reaction were determined.The relative rates of the tertiary C-H-bonds in the sulphochlorination were considerably lower than the corresponding values for the chlorination of the branched-chain paraffins.
Estel, D.,Mateew, K.,Pritzkow, W.,Schmidt-Renner, W.
p. 262 - 268
(2007/10/02)
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