When phosphoryl azide meets mechanochemistry: Clean, rapid, and efficient synthesis of phosphoryl amides under B(C6F5)3catalysis in a ball mill
We described herein the first example associated with B(C6F5)3-catalyzed preparation of phosphoryl amides under mechanochemical conditions. In this novel system, the combination of energetic reagents with an energetic mechanochemical process enabled the r
Transition-metal-free amination phosphoryl azide for the synthesis of phosphoramidates
A facile and efficient approach to phosphoramidates was developed via amination of phosphoryl azides. A variety of phosphoramidates were obtained in one step with good to excellent yields under a mild reaction system. The process uses easily available ami
DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents
Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.
Jones, Caroline S.,Bull, Steven D.,Williams, Jonathan M. J.
p. 8452 - 8456
(2016/09/28)
Efficient amidation and esterification of phosphoric acid using Cl 3CCN/ Ph3P
-
Kasemsuknimit, Atthapol,Satyender, Apuri,Chavasiri, Warinthorn,Jang, Doo Ok
experimental part
p. 3486 - 3488
(2012/01/13)
Nucleophilic Substitution at the Tetracoordinated Phosphorus Atom. Reactivity of Amines towards Diphenyl Chlorophosphate in Acetonitrile
Tertiary alkylamines, pyridines, and imidazoles catalyze the hydrolysis of diphenylchlorophosphate (acetonitrile, 25°C) by a nucleophilic mechanism with the rate-determining attack of an amine on the substrate. Primary and secondary alkyl and arylamines f
Solomoichenko,Sadovskii,Savelova,Piskunova,Popov
p. 1434 - 1441
(2007/10/03)
Diphenylesters of amidophosphoric acids, their synthesis, determination of phosphorus and biological activity
-
Roubinek,Bedrnik,Cech,et al.
p. 90 - 94
(2007/10/08)
More Articles about upstream products of 6214-09-1