A simple route to kinetically unstabilized phosphaalkynes
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Guillemin,Janati,Denis
p. 7864 - 7868
(2007/10/03)
Electrosynthesis of α-arylated β-substituted cyclopropylphosphonates. Synthesis of a phosphonic analogue of minalcipran
(Formula presented) The synthesis of α-arylated β-substituted cyclopropylphosphonates was efficiently achieved by electroreduction of diethyl α,α-dichlorobenzylphosphonate in the presence of Michael acceptors in a one-compartment cell equipped with a magnesium sacrificial anode.