Manganese-catalyzed regiospecific sp3 C-S bond formation through C-C bond cleavage of cyclobutanols
A manganese-catalyzed regioselective sp3 C-S bond formation through C-C bond cleavage of cyclobutanols is described. A variety of primary and secondary alkyl thioethers are efficiently prepared under mild reaction conditions. The mechanistic pathways involving radical-mediated tandem C-C bond cleavage and C-S bond formation are proposed.
Ren, Rongguo,Wu, Zhen,Zhu, Chen
supporting information
p. 8160 - 8163
(2016/07/06)
Synthesis of 2-alkylcyclopentenones. Jasmone, dihydrojasmone, and a prostaglandin precursor.
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Bakuzis,Bakuzis
p. 2362 - 2365
(2007/10/11)
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