62370-46-1

Basic information

• Product Name: 2-{[(4-methoxyphenyl)amino]methylene}-5,5-dimethyl-1,3-cyclohexanedione
• Synonyms: 2-{[(4-methoxyphenyl)amino]methylene}-5,5-dimethyl-1,3-cyclohexanedione
• CAS NO: 62370-46-1
• Molecular Formula: C₁₆H₁₉NO₃
• Molecular Weight: 273.32696
• Mol File: 62370-46-1.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-{[(4-methoxyphenyl)amino]methylene}-5,5-dimethyl-1,3-cyclohexanedione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-{[(4-methoxyphenyl)amino]methylene}-5,5-dimethyl-1,3-cyclohexanedione(62370-46-1)
• EPA Substance Registry System: 2-{[(4-methoxyphenyl)amino]methylene}-5,5-dimethyl-1,3-cyclohexanedione(62370-46-1)

Safety Data

• Hazardous Substances Data: 62370-46-1(Hazardous Substances Data)

Upstream product

• 126-81-8 dimedone 
• 104-94-9 4-methoxy-aniline 
• 122-51-0 orthoformic acid triethyl ester 
• 10349-38-9 p-methoxyphenylisonitrile 

Relevant articles and documents

Metal-free coupling/isomerization reaction of isocyanide and cyclic 1,3-dione: A selective Csp3-H functionalization strategy for C-C bond formation

A metal-free oxidative coupling/isomerization reaction of isocyanide and cyclic 1, 3-dione has been disclosed. In the presence of di-tert-butylperoxide (DTBP), a series of isocyanides are subjected to reaction with subsituted 1, 3-diones for direct synthe

Silver-Catalyzed Cross-Coupling of Isocyanides and Active Methylene Compounds by a Radical Process

Isocyanides are versatile building blocks, and have been extensively exploited in C-H functionalization reactions. However, transition-metal-catalyzed direct C-H functionalization reactions with isocyanides suffer from over-insertion of isocyanides. Repor

Photobleaching Activity of 2-(Phenylamino)methylidenecyclohexane-1,3-diones in Tobacco (Nicotiana tabacum) Cultured Cells

A series of phenylalkylidenecyclohexane-1,3-dione derivatives were designed and synthesized as vinylogous analogs of phthalimides, which are known photobleaching herbicides. The bleaching activity of synthesized compounds was assayed with photomixotrophic tobacco cultured cells under either light or dark conditions. Both the chlorophyll and the carotenoid contents of the cells treated with the cyclic diones decreased to almost zero within 24 h under the light condition but not under the dark condition. This rapid emergence of bleaching activity with light is one of the most distinctive actions of Protox-inhibiting herbicides; however, the cyclic dione did not inhibit protoporphyrinogen oxidase in vitro. Thus, we concluded that the cyclic diones possessed a different herbicidal mode of action from Protox-inhibiting herbicide.