624739-90-8Relevant articles and documents
Domino N-H/C-H bond activation: Copper-catalyzed synthesis of nitrogen-bridgehead heterocycles using azoles and 1,4-dihalo-1,3-dienes
Liao, Qian,Zhang, Liyun,Li, Shutao,Xi, Chanjuan
supporting information; experimental part, p. 228 - 231 (2011/03/19)
Copper-catalyzed tandem coupling of 1,4-dihalo-1,3-dienes with azoles via an N-H bond and its adjacent C-H bond activation has been described. The reaction exhibits good regioselectivity when unsymmetrical 1,4-dihalo-1,3-diene is employed. This method provided a novel route to the synthesis of nitrogen-bridgehead azolopyridine derivatives.
Chromium-mediated synthesis of polycyclic aromatic compounds from halobiaryls
Kanno, Ken-Ichiro,Liu, Yuanhong,Iesato, Atsushi,Nakajima, Kiyohiko,Takahashi, Tamotsu
, p. 5453 - 5456 (2007/10/03)
(Chemical Equation Presented) Reaction of 2,2′-dihalobiphenyl with butyllithium followed by the addition of chromium(III) chloride and alkynes afforded the corresponding phenanthrene derivatives via formal [4 + 2] cycloaddition. A variety of alkynes could be used for this reaction, such as alkyl, aryl, silyl, and alkoxycarbonyl alkynes. Repetitive process of the reaction gave more extended polycyclic compounds such as benzo[g]chrysene and azacyclopentaphenalene derivatives.